Operando spectroscopy
In-situ Raman and ATR-SEIRAS to watch intermediates and cation effects at the reduction interface while the cell runs, not after it dies.
Three threads — selective catalysis, durable interfaces, and honest techno-economics — that together make one carbon-utilization stack.
Each theme answers a different question that stands between a promising lab result and a deployable carbon-utilization technology — catalyst, device, and economics.
Motivation. Copper is the only single metal that couples CO₂-derived intermediates into C2+ products, but on its own it sprays the current across a dozen species and wastes much of it splitting water into hydrogen. Selectivity, not raw activity, is the bottleneck.
Approach. We pair copper with silver in tandem gas-diffusion electrodes so that Ag generates a local supply of CO that Cu then dimerizes, and we use pulsed-potential protocols and cation engineering to hold the active surface in its productive state rather than letting it reconstruct.
Outcome. The flagship Cu–Ag architecture reaches 78% Faradaic efficiency toward C2+ products at 300 mA cm⁻², published in Nature Energy (2025), with operando Raman evidence for the cation effect that drives it.
Motivation. A catalyst that is brilliant for an hour is useless to a plant. At industrial current densities the gas-diffusion layer floods, salts precipitate in the cathode, and selectivity collapses within tens of hours — the failure mode that quietly kills most reported cells.
Approach. We engineer the water and ion balance of membrane-electrode assemblies directly: hydrophobic microporous layers, anion-exchange ionomer loading, and bicarbonate management that keeps the triple-phase boundary dry enough to breathe yet wet enough to conduct.
Outcome. Our flooding-resistant MEAs hold stable C2+ selectivity past 200 hours at 200 mA cm⁻², reported in Joule (2023) — moving the durability conversation from minutes to days.
Motivation. It is easy to spend three years optimizing a product that can never clear its own electricity bill. Before the bench work, the economics should tell us which products, current densities, and selectivities are even worth chasing.
Approach. I build bottom-up techno-economic models that couple cell performance — selectivity, voltage, current density, single-pass conversion — to separation cost and electricity price, then surface the cost floor for each candidate product.
Outcome. "A Techno-Economic Floor for Electrochemical Ethylene" (Energy & Environmental Science, 2024) shows where ethylene becomes competitive and, just as usefully, where it cannot — guidance the lab now uses to pick targets.
A toolkit that spans the catalyst surface, the working device, and the spreadsheet — chosen so that mechanism, performance, and cost can all be measured on the same system.
In-situ Raman and ATR-SEIRAS to watch intermediates and cation effects at the reduction interface while the cell runs, not after it dies.
On-line gas chromatography and GC/MS plus NMR quantification of liquid products to close Faradaic balances across the full C1–C2+ slate.
Spray and airbrush deposition of catalyst inks onto gas-diffusion layers, with controlled ionomer loading and hydrophobic microporous coatings.
Zero-gap and flow-by membrane-electrode assembly reactors for long-duration testing at industrial current densities with controlled humidity.
Microkinetic and continuum transport modeling, informed by density-functional binding energies, to connect surface chemistry to measured selectivity.
Bottom-up cost models linking cell metrics to separation and electricity costs, with Monte Carlo sensitivity on price and performance.
This research is supported by federal fellowships and grants, with institutional backing from The University of Alabama College of Engineering.
Three years of stipend and tuition support for the catalyst-selectivity program.
Award DGE-2137108
Office of Science support for durable MEA development at industrial current density.
DE-SC0023871
Seed funding, shared characterization facilities, and the Outstanding Researcher award (2023).
CBE-SEED-2022-14
Any opinions, findings, and conclusions expressed here are those of the author and do not necessarily reflect the views of the funding agencies.
The program runs on close collaboration inside the Electrochemical Carbon Lab and with partners in spectroscopy, modeling, and scale-up.
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